村田 美樹 Murata Miki

研究者情報
所属 旧学科 - マテリアル工学科
関連ウェブサイト http://www.mtrl.kitami-it.ac.jp/~murata/index.html
学位・学歴・職歴

学位

博士(工学) Syntheses of Organometallic Compounds of Group 13 and 14 Elements by Transition Metal-Catalyzed Carbon-Metal Bond-Forming Reactions 2000

学歴

1993.3 北見工業大学工学部工業化学科 卒業
1995.3 北海道大学大学院工学研究科応用化学専攻修士課程 修了

職歴

1995.4 北見工業大学工学部機能材料工学科助手
2004.10 北見工業大学工学部機能材料工学科助教授
2007.4 北見工業大学工学部機能材料工学科准教授
2008.4 北見工業大学工学部マテリアル工学科准教授
2013.4 北見工業大学工学部マテリアル工学科教授
担当科目・専門分野等
担当授業科目(学部)
工学基礎実験および演習 地域未来/短期履修, 化学II 地球環境, 有機化学I 先端材料物質/短期履修, 文献ゼミナール マテ, 先端材料工学 マテ, 先端材料物質工学概論/短期履修, 地球環境工学入門
担当授業科目(大学院)
有機材料特論Ⅱ マテ
専門分野
有機合成化学, 有機金属化学
研究テーマ
遷移金属触媒を用いる新規結合形成反応の開発
研究内容キーワード
遷移金属触媒, 有機ホウ素化合物, 有機ケイ素化合物, 和種ハッカ
所属学会
日本化学会, 有機合成化学協会
著書
タイトル/出版社等
Organic Syntheses, Collect. Vol. X, pp 115-120, Bis(pinacolato)diboron (2,2’-Bi-1,3,2-dioxaborolane, 4,4,4’,4’,5,5,5’,5’-octamethyl-)
Wiley: New York, 2004-03
有機ボロン酸およびその誘導体合成の動向、クロスカップリング反応−基礎と産業応用−
シーエムシー出版, 2010-11
B−CおよびSi−C結合形成の新展開、現代化学増刊44 有機金属化学最前線
東京化学同人, 2011-03
“C–B and C–Si Bond Forming Reactions of C–X Electrophiles”, Science of Synthesis Reference Library: Cross-Coupling and Heck-type Reactions, Larhed, M.; Molander, G. A.; Wolfe, J. P. Eds. Vol. 2, pp.439-483.
Thieme: Stuttgart, 2012-11
学術論文等

学術論文

論文名/掲載誌名等     掲載年月
Palladium-Catalyzed Cross-Coupling Reaction of Aryltriethoxysilanes with Aryl Bromides under Basic Aqueous Conditions
Synthesis, 15, 2231-2233
2001-11
Synthesis and characterization of aromatic polyimide containing 3,6-diamino-9-alkylcarbazole and aromatic tetracarboxylic dianhydrides
High Performance Polymers, 13, 4, 281-286
2001-12
Formation of (Z)-Allylboronates via Ruthenium-Catalyzed Hydroboration of Propargyl Ethers with Pinacolborane
Journal of Chemical Research (S), 3, 142-143
2002-03
Rhodium- and Ruthenium-Catalyzed Dehydrogenative Borylation of Vinylarenes with Pinacolborane: Stereoselective Synthesis of Vinylboronates
Bulletin of the Chemical Society of Japan, 75, 4, 825-829
2002-04
Rhodium(I)-Catalyzed 1,2- and 1,4-Addition of Aryltriethoxysilanes to Carbonyl Compounds under Basic Aqueous Conditions
Synthesis, 6, 717-719
2002-05
Rhodium(I)-Catalyzed Silylation of Aryl Halides with Triethoxysilane: Practical Synthetic Route to Aryltriethoxysilanes
Organic Letters, 4, 11, 1843-1845
2002-05
Synthesis of Benzylboronates via Palladium-Catalyzed Borylation of Benzyl Halides with Pinacolborane
Synthetic Communications, 32, 16, 2513-2517
2002-11
Synthesis of Polymer Microspheres with Mercapto Groups by Polycondensation of 1,3-Propanedithiol and 1,6-Dibromohexane in the Presence of a Poly[styrene-alkylacrylamide] Latex
Polymer Journal , 36, 1, 45-49
2004-01
A General and Efficient Method for the Palladium-Catalyzed Cross-Coupling of Thiols and Secondary Phosphines
Tetrahedron, 60, 34, 7397-7403
2004-08
An Efficient Catalyst System for Palladium(0)-Catalyzed Cross-Coupling of Aryltrialkoxysilanes with Aryl Halides
Synlett, 1, 118-120
2006-01
Preparation of Polystyrene-Polyimide Particles by Dispersion Polymerization of Styrene Using Poly(amic acid) as a Stabilizer
Polymer J., 38, 471-476
2006-05
Palladium(0)-Catalyzed Silylation of Aryl Halides with Triorganosilanes: Synthesis of Aryl(2-furyl)silanes
Synthesis, 11, 1771-1774
2006-05
An Efficient Catalyst System for Palladium-Catalyzed Borylation of Aryl Halides with Pinacolborane
Synlett, 12, 1867-1870
2006-08
Aromatic C-H Borylation Catalyzed by Hydrotris(pyrazolyl)borate Complexes of Rhodium and Iridium
Bull. Chem. Soc. Jpn., 79, 12, 1980-1982
2006-12
4,4,6-Trimethyl-1,3,2-dioxaborinane: A Practical Reagent for Palladium-Catalyzed Borylation of Aryl Halides
Synthesis, 3, 351-354
2007-02
Synthesis of aryltriethoxysilanes via rhodium(I)-catalyzed cross-coupling of aryl electrophiles with triethoxysilane
Tetrahedron, Available online 25 February 2007, 63
2007-02
Synthesis of aryltriethoxysilanes via rhodium(I)-catalyzed cross-coupling of aryl electrophiles with triethoxysilane
Tetrahedron, 63, 4087-4094
2007-05
Silylation of Aryl Iodides with 1,1,1,3,5,5,5-Heptamethyltrisiloxane Catalyzed by Transition Metal Complexes
Synlett, 1387-1390
2007-06
Platinum-catalyzed Aromatic C-H Silylation of Arenes with 1,1,1,3,5,5,5-Heptamethyltrisiloxane
Chem. Lett., 36, 910-911
2007-07
Synthesis of Organosilatranes via Rhodium(I)-Catalyzed Silylation of Organic Iodides with Hydrosilatrane
Synthesis, 2944-2946
2007-10
重縮合を用いたアミノ基をもつ異形高分子微粒子の合成
高分子論文集, 64, 683-687
2007-10
Preparation of Poly(t-butyl methacrylate)-Polyimide Particles by Dispersion Polymerization of t-Butyl Methacrylate Using Poly(amic acid) as a Stabilizer and Subsequent Imidization
Polymer J., 40, 743-748
2008-08
Palladium- or Nickel-Catalyzed Coupling Reaction of Dialkoxyboranes with Chloroarenes: Arylation of 1,3,2-Dioxaborolanes or 1,3,2-Dioxaborinanes
Heterocycles, 80, 213-218
2010-01
ヒドロシラン/遷移金属錯体による有機ハロゲン化物の触媒的ケイ素化
有機合成化学協会誌, 68, 8, 845-853
2010-08
Preparation of monodisperse PMMA particles by dispersion polymerization of MMA using poly(styrene-co-methacrylic acid) copolymer as a steric stabilizer
Polym. Bull., 65, 543-550
2010-09
Palladium-Catalyzed Borylation of Aryl Arenesulfonates with Dialkoxyboranes
Chem. Lett., 40, 962-963
2011-09
Ruthenium-Catalyzed Ortho-Selective Aromatic C–H Silylation: Acceptorless Dehydrogenative Coupling of Hydrosilanes
Chem. Lett., 41, 374-376
2012-04
Synthesis of Aryl Triolborates via Nickel-Catalyzed Borylation of Aryl Halides with 5-(t-Butyldimethylsiloxymethyl)-5-methyl-1,3,2-dioxaborinane
Synthesis, 44, 1233-1236
2012-04
Transition-Metal-Catalyzed Borylation of Organic Halides with Hydroboranes
Heterocycles, 85, 1795-1819
2012-08
Nickel-Catalyzed Borylation of Aryl Halides with 4,4,6-Trimethyl-1,3,2-dioxaborinane
Heterocycles, 86, 133-138
2012-12
Preparation of aliphatic polypyromellitimide particles by polycondensation of nylon-salt-type monomers derived from aliphatic diamines with diethyl pyromellitate in ethylene glycol
High Perform. Polym., 24, 710–716
2012-12
Palladium-Catalyzed Borylation of Aryl Iodides with 2,3-Dihydro-1H-benzo[d][1,3,2]diazaboroles
Heterocycles, 88, 133-138
2014-01
Preparation of aliphatic-aromatic polyimide particles by polycondensation of diethyl hexafluoroisopropylidenediphthalate and diaminooctane in ethylene glycol
High Performance Polymers, 27, 2, 183-190
2015-03
Ruthenium-Catalyzed Ortho-Selective Aromatic C–H Borylation of 2-Arylpyridines with Pinacolborane
ChemCatChem, 7, 10, 1531-1534
2015-05
Ruthenium-Catalyzed Dehydrogenative Aromatic C–H Silylation of Benzamides with Hydrosilanes
Adv. Synth. Catal., 357, 10, 2229-2232
2015-07
チエニル基を有するビニルエーテルのリビングカチオン重合
高分子論文集, 72, 7, 433-439
2015-07
イミノ基により架橋した分解性ポリ(アルキルビニルエーテル)ゴムの合成
高分子論文集, 73, 2, 213-220
2016-03
Site-Selective Aliphatic C—H Silylation of 2-Alkyloxazolines Catalyzed by Ruthenium Complexes
ChemCatChem, 8, 2202-2205
2016-06
Ruthenium-catalysed dehydrogenative C—H borylation of arenes with pinacolborane
J. Chem. Res., 40, 393-396
2016-07
Synthesis of Dibenzosiloles via Platinum-Catalyzed Intramolecular Dehydrogenative Cyclization of 2-(Dialkylsilyl)biaryls
Chem. Lett., 45, 857-859
2016-08
Rhodium(I)-Catalyzed Silylation of Aryl Iodides with Di(2-furyl)methylsilane
Heterocycles, 95, 152-157
2017-04
Ruthenium-catalyzed nitrogen-directed ortho C—H borylation of aromatic imines with pinacolborane
Tetrahedron Letters, 59, 26, 2537-2540
2018-06
Utilization of the Japanese Peppermint Herbal Water Byproduct of Steam Distillation as an Antimicrobial Agent
Journal of Oleo Science, 67, 10, 1227-1233
2018-10
Unnatural tripeptide as highly enantioselective organocatalyst for asymmetric aldol reaction of isatins
Tetrahedron Letters, 60, 5, 415-418
2019-01
Tripeptide-catalyzed Asymmetric Aldol Reaction of Trifluoromethylated Aromatic Ketones with Acetone
Heterocycles, 99, 2, 841-847
2019-02
Preparation of monodisperse fully aromatic polyimide particles via the polycondensation of diethyl hexafluoroisopropylidenediphthalate with 4,4′-diaminodiphenylether in ethylene glycol
Polymer Journal, 51, 405-412
2019-03

参考論文

論文名/掲載誌名等 掲載年月
十字路:σ結合メタセシス
有機合成化学協会誌, 68, 8, 870
2010-08

国際会議発表論文

発表題名 発行年月
Development of unnatural tripeptide as highly enantioselective organocatalyst for asymmetric aldol reaction of isatins
The 14th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-14), Kinka Chemical Society, Kyoto
2018-11
A Heterogeneous Ru Catalyst for Site-Selective C–H Borylation
The 14th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-14), Kinka Chemical Society, Kyoto
2018-11
科学研究費
研究課題・他 取得年月
ホウ素-水素結合活性化に基づく直截的ホウ素基導入反応の反応制御とその応用
2011年4月28日-2014年3月31日
ホウ素-水素結合活性化に基づく直截的ホウ素基導入反応の反応制御とその応用
ホウ素-水素結合活性化に基づく直截的ホウ素基導入反応の反応制御とその応用
受賞
2004 有機合成化学協会研究企画賞
2005 日本化学会北海道支部奨励賞