坂上 寛敏 Sakagami Hirotoshi

研究者情報
職名 助教
所属 地球環境工学科 - エネルギー総合工学コース
生年月日 1971年11月10日
電話番号 0157-26-9449
ファックス 0157-26-4973
学位・学歴・職歴

学位

博士(工学) 貴金属担持触媒のC−C結合形成に対する触媒特性 2014
担当科目・専門分野等
担当授業科目(学部)
エネルギー総合工学概論/短期履修, 化学エネルギー基礎 エネルギー総合, エネルギー工学実験I エネルギー総合, 先端材料物質総合工学I 先端材料物質, オホーツク地域と環境 地球環境, オホーツク地域と環境 地域未来, 安全工学概論 地球環境, 安全工学概論 地域未来, 地球環境工学入門, 先端材料工学 マテ, 先端材料工学 マテ, エネルギー総合工学I エネルギー総合, エネルギー総合工学I エネルギー総合
専門分野
触媒化学, 有機化学
研究内容キーワード
担持触媒, 不均一系触媒反応, ロジウム, パラジウム, 活性炭, シリカゲル, ガスハイドレート
所属学会
日本化学会, 触媒学会, 石油学会, 日本分析化学会, 石油技術協会
学術論文等

学術論文

論文名/掲載誌名等     掲載年月
Effects of rhodium dispersion on catalytic behavior of Rh/active carbon catalysts for H/D exchange reaction between CH4 and D2
Phys. Chem. Chem. Phys., 3, 10, 1930-1934
2001-05
Thermal stability of porous MoOx and its catalytic property for the conversion of 2-propanol
Appl. Catal. A: General, 213, 83-90
2001-05
H2-reduction of Pt/MoO3 to MoOx with a large surface area and its catalytic activities for the conversions of heptane and propa-2-ol
Phys. Chem. Chem. Phys., 3, 19, 4430-4436
2001-09
Formation of MoOx with a large surface area by H2 reduction of MoO3 in the presence of Pt
Microporous and Mesoporous Materials, 51, 155-164
2002-01
Effect of the flow rate of H2 in the reduction process on the physical and catalytic properties of H2-reduced Pt/MoO3
Bull. Chem. Soc. Jpn., 75, 5, 1165-1171
2002-05
Catalytic properties of H2-reduced MoO3 and Pt/zeolites for the isomerization of pentane hexane and heptane
Appl. Catal. A: General, 242, 267-274
2003-03
Pentane Isomerization over Molybdenum Oxide Prepared by H2 Reduction of a Hydrogen Molybdenum Bronze
Chem. Lett., 32, 6, 556-557
2003-06
H2-reduced Pt/MoO3 as a selective catalyst for heptane isomerization
Catalysis Today, 81, 31-42
2003-06
Comparison of the catalytic properties of H2-reduced Pt/MoO3 and of Pt/zeolites for the conversions of pentane and heptane
Appl. Catal. A: General, 248, 269-278
2003-08
Comparison of dinitrodiamminepalladium with palladium nitrate as a precursor for Pd/SiO2 with respect to catalytic behavior for ethane hydroformylation and carbon monoxide hydrogenation
Catal. Lett., 99, 3-4, 257-261
2005-02
H2 reduction of hydrogen molybdenum bronze to porous molybdenum oxide and its catalytic properties for the conversions of pentane and propan-2-ol
Appl. Catal. A: General, 284, 1-2, 123-130
2005-04
Lattice Expansion of Clathrate Hydrates of Methane Mixtures and Natural Gas
Angewandte Chemie International Edition, 44, 42, 6928-6931
2005-10
Reduction of HxMoO3 with different amounts oh hydrogen to high surface area molybdenum oxides
Appl. Catal. A: General, 297, 2, 189-197
2006-01
Structure and thermal expansion of natural gas clathrate hydrates
Chemical Engineering Science, 61, 8, 2313-2752
2006-01
The effects of Na loading on catalytic properties of H2-reducted Pt/MoO3 for Heptane isomerization
J. Catal., 263-303, 2, 241
2006-10
Coexistence of structure I and II gas hydrates in Lake Baikal suggesting gas sources from microbial and thermogenic origin
Geophys. Res. Lett., L24603, 33
2006-12
Estimation of Gas Composition and Cage Occupancies in CH4 - C2H6 Hydrates by CP-MAS 13C NMR Technique
Journal of the Japan Petroleum Institute, 50, 3, 132-138
2007-05
Reduction of MoO3 to Porous Molybdenum Oxides and Its Catalytic Properties for Alkane Isomerization
Journal of the Japan Petroleum Institute, 50, 5, 229-239
2007-09
Isotopic fractionation of methane and ethane hydrates between gas and hydrate phases
Geophysical research letters, 34, L21502
2007-11
Chemical composition of the pore waters in the bottom sediments of Lake Baikal
Russian Geology and Geophysics, 48, 11, 886-900
2007-11
オホーツク海のメタンハイドレート含有層における間隙水の地球化学
地学雑誌, 118, 1, 194-206
2009-03
オホーツク海天然ガスハイドレートの同位体組成とその結晶特性
地学雑誌, 118, 1, 207-221
2009-03
Natural gas hydrates with locally different cage occupancies and hydration numbers in Lake Baikal
Geochem. Geophys. Geosyst., 10, Q05003, doi:10.1029/2009GC002473
2009-05
Effects of the amount of MoO3 on the catalytic properties of H2-reduced Pt/MoO3-SiO2 for heptane isomerization
Appl. Catal. A: General, 362, 40180, 51-72
2009-06
Gas hydrate forming fluids on the NE Sakhalin slope, Sea of Okhotsk
Geological Union, 319, 51-72
2009-08
Characteristics of Natural Gas Hydrates Occurring in Pore-Spaces of Marine Sediments Collected from the Eastern Nankai Trough, off Japan
Energy Fuels, 23, 11, 5580-5586
2009-09
Dissociation heat of mixed-gas hydrate composed of methane and ethane
雪氷, 71, 5, 341-351
2009-09
Model of formation of double structure gas hydrates in Lake Baikal based on isotopic data
Geophysical Research Letters, 36, L18504, doi:10.1029/2009GL039805
2009-09
Isotopic composition of gas hydrates in subsurface sediments from offshore Sakhalin Island, Sea of Okhotsk
Geo-Mar. Lett., in press
2010-03
Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal
Geo-Mar. Lett., in press
2010-03
Heptane isomerization over molybdenum oxides obtained by H2 reduction of HxMoO3 with different hydrogen contents
Appl. Catal. A: General, 389, 1-2, 52-59
2010-09
摩周湖水中ニッケル及びバナジウム濃度の深度プロファイルと大気経由人為起源ニッケル及びバナジウム供給の可能性
分析化学, 59, 12, 1105-1111
2010-12
13C Chemical Shifts of Propane Molecules Encaged in Structure II Clathrate Hydrate
J. Phys. Chem. A, 115, 5, 643-647
2011-01
Development of determination method of trace nickel in natural water by ID-oxygen added nitrogen-MIP-MS with direct measurement of liquid-liquid extracted organic phase
Int. J. Environ. Anal. Chem., 91, 9, 811-820
2011-08
Molecular and isotopic composition of hydrate-bound gases and sediment gases by an improved headspace gas method at the southern basin of Lake Baikal
Geo-Marine Letters, 32, 5-6, 465-472
2012-11
Possible variation in methane flux caused by gas hydrate formation off Sakhalin Island, Russia
Geo-Marine Letters, 32, 5-6, 525-534
2012-11
Raman spectroscopic and calorimetric observations on natural gas hydrates obtained from southern and central Lake Baikal
Geo-Marine Letters, 32, 5-6, 416-426
2012-11
表層型ガスハイドレート賦存海底・湖底地盤から採取した堆積土の土質特性 -間隙水溶存ガスの気化に伴う堆積土の試料乱れ評価-
地盤工学ジャーナル, 7, 4, 503-516
2012-12
Methane Clathrate Hydrates Formed within Hydrophilic and Hydrophobic Media: Kinetics of Dissociation and Distortion of Host Structure
J. Phys. Chem. C, 117, 14, 7081-7085
2013-04
Chemical Shift Changes and Line Narrowing in 13C NMR Spectra of Hydrocarbon Clathrate Hydrates
J. Phys. Chem. A, 117, 20, 4108-4114
2013-04
Physical and catalytic properties of Pt/MoO3 reduced at different H2 flow rates
Applied Catalysis A: General, 470, 8-14
2014-01
Sequentially sampled gas hydrate water, coupled with pore water and bottom water isotopic and ionic signatures at the Kukuy mud volcano, Lake Baikal: ambiguous deep-rooted source of hydrate-forming water
Geo-Marine Letters, 34, 2-3, 241-251
2014-06
Distribution of butane in the host water cage of structure ii Clathrate hydrates
Chemistry - A European Journal, 20, 51, 17207-17213
2014-12
Structural properties of methane and butane mixed-gas hydrates
Chemical Engineering Science, 140, 10-15
2016-02
Synthesis of Dibenzosiloles via Platinum-Catalyzed Intramolecular Dehydrogenative Cyclization of 2-(Dialkylsilyl)biaryls
Chem. Lett., 45, 857-859
2016-08
Hydrogen and oxygen isotopic anomalies in pore waters suggesting clay mineral dehydration at gas hydrate-bearing Kedr mud volcano, southern Lake Baikal, Russia
Geo-Marine Letters, 38, 403-415
2018-07
道東沖オホーツク海海底地盤における重力式コーン貫入試験
土木学会論文集B3(海洋開発), 74, 2, I_868-I_873
2018-09

参考論文

論文名/掲載誌名等 掲載年月
Hydrate-Bearing Structures in the Sea of Okhotsk
EOS, Transactions, American Geophysical Union, 86, 2, 13-24
2005-01
Hydrogeochemical and isotopic signatures of gas hydrate-forming fluids offshore NE Sakhalin (the Sea of Okhotsk): Results from the CHAOS-2003 cruises
Proceedings of the Fifth International Conference on Gas Hydrates, 3, 931-936
2005-06
Some ion concentration profiles in pore water samples from gas hydrate-bearing sediments offshore Sakhalin
Proceedings of the Fifth International Conference on Gas Hydrates, 3, 1049-1051
2005-06
Video-camera observations of tiny gas bubbles in deep water
Proceedings of the Fifth International Conference on Gas Hydrates, 3, 1086-1088
2005-06
PHASE EQUILIBRIUM AND COMPARISON OF FORMATION SPEEDS OF CH4 AND CO2 HYDRATE BELOW THE ICE POINT
Proceedings of the Fifth International Conference on Gas Hydrates, 1, 274-278
2005-06
CP-MAS 13C-NMR study on the crystallographic structure on natural gas hydrate
Proceedings of the Fifth International Conference on Gas Hydrates, 2, 497-501
2005-06
13C-NMRによる天然ガスハイドレートの結晶学的評価
月刊地球, 27, 12, 971-975
2005-11
サハリン沖LV32海底表層コア間隙水中の各種化学成分の測定
月刊地球, 27, 12, 901-905
2005-11
未利用エネルギー・メタンハイドレート開発 -特に表層型メタンハイドレートについて-
機械の研究, 57, 12, 1235-1240
2005-12
Hydration number determinations of natural gas hydrates using 13C-NMR
Proceedings of the 2nd International Workshop on Gas Hydrate Studies and Other Related Topics -for the Future Energy and Environment Conciderations-, 97-102
2007-04
Chemical analysis of sediment cores offshore Sakhalin, Okhotsk Sea
Proceedings of the 2nd International Workshop on Gas Hydrate Studies and Other Related Topics -for the Future Energy and Environment Conciderations-, 57-59
2007-04
Gas fractionation experiments of CH4 and CO2 mixed-gas hydrate below freezing point of water
Proceedings of the 2nd International Workshop on Gas Hydrate Studies and Other Related Topics -for the Future Energy and Environment Conciderations-, 185-188
2007-04
A video-camera device for small bubble observations in deep water near gas hydrate accumulations
Proceedings of the 2nd International Workshop on Gas Hydrate Studies and Other Related Topics -for the Future Energy and Environment Conciderations-, 193-196
2007-04
Chemical and isotopic characteristics of gas hydrate- and pore- water samples obtained from gas hydrate-bearing sediment cores retrieved from a mud volcano in the Kukuy canyon, Lake Baikal
Proceedings of the 6th International Conference on Gas Hydrates
2008-07
Cage occupancies of natural gas hydrates encaging methane and ethane
Proceedings of the 6th International Conference on Gas Hydrates
2008-07
Fromation process of structure I and II gas hydrates discovered in Kukuy, Lake Baikal
Proceedings of the 6th International Conference on Gas Hydrates
2008-07
Isotopic and chemical composition of gas hydrate water samples retrieved at mud volcanoes in Lake Baikal, Russia
Proceedings of the International Workshop in Modern Science and Technology, 111-114
2008-11
Determination of Nickel in Natural Water by Solvent Extraction/Direct Introduction - Isotope Dilution Microwave Induced Oxygen - Nitrogen Plasma Mass Spectrometry
Proceedings of the International Workshop in Modern Science and Technology, 115-119
2008-11
CP-MAS 13C NMR法によるメタン‐エタン混合ガスハイドレートのガス組成およびケージ占有率評価
ペトロテック, 32, 8, 555-559
2009-08
ガスハイドレート生成時のゲストガス同位体分別-バイカル湖の天然ガスハイドレートの例-
北海道の雪氷(日本雪氷学会北海道支部機関誌), 28, 61-65
2009-08
バイカル湖天然ガスハイドレートのゲストガス同位体比
月刊地球, 31, 9, 486-492
2009-09
バイカル湖南湖盆の結晶構造II型天然ガスハイドレート
北海道の雪氷(日本雪氷学会北海道支部機関誌), 35, 95-98
2016-09
メタン・硫化水素混合ガスハイドレートにおけるゲストガス分子の占有性
北海道の雪氷(日本雪氷学会北海道支部機関誌), 36, 89-92
2017-09
天然ガスハイドレート生成時のメタン炭素安定同位体分別 ―バイカル湖南湖盆のハイドレート含有湖底堆積物の例―
北海道の雪氷(日本雪氷学会北海道支部機関誌), 36, 85-88
2017-09
海底地盤における重力式コーン貫入試験の適用性
第9回メタンハイドレート総合シンポジウム講演集, 37-42
2017-10
バイカル湖南湖盆に産する天然ガスハイドレートの特徴について
第9回メタンハイドレート総合シンポジウム講演集, 55-57
2017-10
オホーツク海網走沖のガス湧出域におけるROV調査概要
第9回メタンハイドレート総合シンポジウム講演集, 43-47
2017-10
オホーツク海枝幸沖および網走沖のガスプルームに関する地球化学的特徴
第9回メタンハイドレート総合シンポジウム講演集,, 52-54
2017-10
オホーツク海海底地盤における重力式コーン貫入試験
地盤工学会北海道支部技術報告集, 58, 205-212
2018-01
北海道周辺海域海底地盤における重力式コーン貫入試験
地盤工学会北海道支部技術報告集, 59, 85-92
2019-01
科学研究費
研究課題・他 取得年月
ガスハイドレート生成に伴う包接炭化水素分子の安定同位体分別過程の解明
ガスハイドレート生成に伴う包接炭化水素分子の安定同位体分別過程の解明
ガスハイドレート生成に伴う包接炭化水素分子の安定同位体分別過程の解明
ガスハイドレート包接炭化水素分子と気相炭化水素分子の交換挙動の解明
ガスハイドレート包接炭化水素分子と気相炭化水素分子の交換挙動の解明