星 雅之 Hoshi Masayuki

研究者情報
職名 教授
所属 地域未来デザイン工学科 - バイオ食品工学コース
電話番号 0157-26-9403
ファックス 0157-24-7719
メールアドレス hoshims@mail.kitami-it.ac.jp
学位・学歴・職歴

学位

工学博士(北海道大学) Study on Organic Synthesis Using Alkenylboranes 1988

学歴

1974 北見工業大学工業化学科入学
1978 北見工業大学工業化学科卒業

職歴

1978-1985 北見工業大学文部技官(教務職員)
1985-1992 北見工業大学工学部助手
1992-2004 北見工業大学工学部助教授
2004-2007 国立大学法人北見工業大学工学部助教授
2007-2009 国立大学法人北見工業大学工学部准教授
2009- 国立大学法人北見工業大学工学部教授
担当科目・専門分野等
担当授業科目(学部)
地域未来デザイン工学入門, 化学I 地域未来, 有機化学I バイオ食品, 有機化学演習 バイオ, ゼミナール バイオ, 英語文献講読 バイオ
担当授業科目(大学院)
材料と物質 創成と評価, 精密合成化学 バイオ/短期履修
専門分野
有機合成化学, 有機金属化学
研究テーマ
有機金属化合物の合成, 有機金属化合物を経由する精密有機合成
研究内容キーワード
有機金属, 合成, 高選択性
所属学会
日本化学会, 有機合成化学協会, アメリカ化学会
学術論文等

学術論文

論文名/掲載誌名等     掲載年月
Construction of terminal conjugated enynes: Regio- and stereoselective syntheses of 3-alken-1-ynes and 1-trimethylsilyl-3-alken-1-ynes from alkenyldialkylboranes and (trimethylsilyl)ethynyl bromide.
Synlett, 7, 1101-1104
2002-07
Transfer of alk-1-enyl group from boron to aluminium: a novel way to prepare (E)-alk-1-enyldiisobutylalanes.
Chem. Commun., 18, 2146-2147
2002-09
Preparation of (E)-1-alkenylboronic acid pinacol esters via transfer of alkenyl group from boron to boron.
Synthesis, 11, 1814-1820
2004-08
Electrooxidative conversion of dibenzoylbenzene dihydrazones into the corresponding bis-diazo compounds and bis-dimethyl acetals.
Aust. J. Chem. , 58, 7, 560-563
2005-07
Stereoselective syntheses of (E)- and (Z)-1-arylalk-3-en-1-ynes and (E,E)-, (Z,E)-, (E,Z)-, and (Z,Z)-alk-1,5-dien-3-ynes via a one-pot multicomponent coupling reaction.
Synthesis, 12, 1991-2007
2005-08
Anodic cyanation of β-dicarbonyl compounds.
Synlett, 16, 2507-2509
2005-10
Construction of terminal conjugated enynes: Cu-mediated cross-coupling reaction of alkenyldialkylborane with (trimethylsilyl)ethynyl bromide.
Synthesis, 12, 1961-1970
2006-06
Electrochemical cyclization of dimethyl aminomalonates
Synlett, 11, 1753-1755
2006-07
Electrooxidative cyclization of hydroquinolyl alcohols
Heterocycles, 68, 12, 2563-2570
2006-12
Synthesis of bis(alk-3-en-1-ynyl)benzene with either E- or Z-configuration via a one-pot three component coupling reaction and its optical properties
Tetrahedron Lett., 48, 1, 119-124
2007-01
Electrooxidative cyclization of hydroquinolyl alcohols, hydroquinolylamines, and dimethyl aminomalonates
Aust. J. Chem., 60, 4, 236-242
2007-04
Generation of bis(pentafluorophenyl)borane-dimethyl sulfide complex as a solution of hexane and its application to hydroboration of alk-1-yne with pinacolborane
Tetrahedron Lett., 48, 48, 8475-8478
2007-11
Electrooxidative cyclization of benzylideneaminothiophenols to the corresponding 2-arylbenzothiazoles
Heterocycles, 75, 1, 35-42
2008-01
Anodic oxidation of ketone allylhydrazones into the corresponding azines
Synthetic Communications, 38, 19, 3320-3328
2008-10
One-pot synthesis of internal conjugated (Z)-enynyltrimethylsilanes possessing aryl, cycloalkenyl, (E)- or (Z)-alk-1-enyl moieties on the sp carbon atom via two types of cross-coupling reaction
Synthesis, 22, 3591-3600
2008-11
Anodic ring-opening reaction of 4-phenyl-2H-phthalazin-1-one into methyl o-(α-methoxy and α-cyano)benzyl-substituted benzoates
Heterocyclic Communications, 14, 6, 461-464
2008-12
Novel application of an electrooxidative method for the formation of a tetrahydrofuran ring from 5-hydroxy-2-pentanone phenylhydrazone
Heterocycles, 78, 6, 1427-1432
2009-06
Transfer of alk-1-enyl group from boron to tin: A highly stereoselective synthesis of (E)-alk-1-enyltributylstannanes
Synlett, 18, 2945-2948
2009-11
One-pot synthesis of conjugated (E)-enynones via two types of cross-coupling reaction
Synlett, 16, 2461-2464
2010-10
Novel application of electrooxidative method for the cyclization of N-benzyl-2-(hydroxymethyl)- and N-benzyl-2-(hydroxyethyl)piperidines
Heterocycles, 81, 11, 2471-2478
2010-11
Successful application of indirect electrooxidation for the transformation of biaryl methanols to the corresponding biaryl ketones.
Synthtic Communications, 41, 21, 3134-3139
2011-10
Homo- and heterocoupling of terminal conjugated enynes: One-pot synthesis of alka-1,7-diene-3,5-diynes and alk-1-ene-3,5-diynes via two types of coupling reaction.
Synthesis, 23, 3839-3847
2011-12
Electrooxidative cyclization of hydroxyamino compounds possessing a benzyl group.
Synthesis, 44, 9, 1315-1322
2012-05
Anodic cyclization of 1,7-diarylheptane-1,7-diones to the corresponding 1,2-diaroylcyclopentanes.
Synlett, 23, 17, 2544-2548
2012-10
Unexpected formation of novel oxazolidine and tetrahydrooxazine derivatives by condensation of 2-(hydroxymethy) or 2-(2-hydroxyethyl)piperidine, and ketones.
Bulg. Chem. Commun., 44, 4, 314-317
2012-12
Anodic cleavage of several ketone N-phenylsemicarbazones into methyl N-phenylcarbamate and the corresponding dimethyl acetals
Synthetic Communications, 43, 13, 1766-1771
2013-04
Anodic cyclization of dimethyl 2-(3-oxo-3-arylpropyl)malonates into the corresponding dimethyl 2-aroylcyclopropane-1,1-dicarboxylates
Synlett, 24, 12, 1568-1572
2013-07
One-pot synthesis of 1-arylmethyl-4-[(E)-alk-1-enyl]-1H-1,2,3-triazoles via a cross-coupling/click reaction sequence
RSC Advances, 4, 5, 2124-2128
2014-01
Anodic cyclization of dimethyl 2-(5-aryl-5-oxopentyl)malonates into the corresponding dimethyl 2-aroylcyclopentane-1,1-dicarboxylates
Tetrahedron Letters, 55, 7, 1299-1302
2014-02
Synthesis of hydroxycinnamoyl β-D-xylopyranosides and evaluation of their antioxidant properties
Carbohydrate Research, 388, 138-146
2014-03
Preparation of optically pure δ-lactones using diastereomeric resolution with amino acid as resolving agent.
Journal of Oleo Science, 64, 1, 75-90
2015-01
Simple preparation of aryltributylstannanes and its application to one-pot synthesis of diaryl ketones
Tetrahedron, 71, 11, 1705-1711
2015-03
Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active δ-hexadecalactone
Journal Oleo Science , 64, 5, 561-575
2015-05
Preparation of optically active 4-substituted,γ-lactones by lipase-catalyzed optical resolution
Heterocyclic communications , 21, 3, 165-174
2015-06
Preparation of optically active δ-tri- and δ-tetradecalactones by a combination of Novozym 435-catalyzed enantioselective methanolysis and amidation
Journal of Oleo Science , 64, 11, 1213-1226
2015-11
First synthesis of both 1-aryl-4-[(E)-alk-1-enyl]-1H-1,2,3-triazoles and 1-aryl-4-[(Z)-1-(trimethylsilyl)alk-1-enyl]-1H-1,2,3-triazoles: assembly of π-extended 1,2,3-triazoles using a cross-coupling/click reaction sequence
Tetrahedron, 72, 29, 4205-4213
2016-06
Synthesis, odour characteristics and antibacterial activities of the stereoisomeric forms of whisky lactone and its thiono analogues
Flavour Fragrance Journal, 32, 29-35
2017-01
Synthesis of various β-D-glucopyranosyl and β-Dxylopyranosyl hydroxybenzoates and evaluation of their antioxidant activities
Heterocyclic Communications, 23, 3, 213-223
2017-07
Synthesis of dibenzothiazepine analogues by one-pot S-arylation and intramolecular cyclization of diaryl sulfides and evaluation of antibacterial properties
Heterocycl. Commun., 24, 4, 219-230
2018-08
科学研究費
研究課題・他 取得年月
アルキルラジカルの付加反応を利用する新規なアルキルボランの合成
1994-1995
アルケニルホウ素化合物を利用する末端共役エンインの立体選択的合成
2001-2002
社会活動
2011~ 北見市緑化審議会会長
2015~ 北見市環境審議会会長
2015~ 北見市廃棄物減量等推進審議会会長